Lance, I do follow you in saying that somehow the plants were deficient in N if they green up by N addition. My point is how quick it is and the effect overwhelmed me. Even plants growing like weed changed significantly - over night- getting much greener and shinier.It seems to work a little like that stuff housewifes spray on plants to meke them shine "leaf-gloss" or whatever its called. Well it had that effect - and over night. And without any of the stuff getting into the soil. Truly amazing. Whether that is something to aim for is another thing, to me its a bit like putting the plants on steroids - but I like it:evil:.
About the missing ppm: Firstly a disclaimer: My numbers are approximate. Then the reason for the deviation: Over here(Norway, Europe), NPK is given as the elements Nitrogen-Phosphorous-K(potassium): in USA (could be all English-speaking countries for what I know?) and some other places its actually as the oxides: N-P2O5-K2O even if they write NPK.
So my 90-10-40 European NPK is 90-23-48 US NPK. Its confusing, right? You have to take the molar weight of the individual components into consideration doing this transformation. Accordingh to my calculation the factor becomes 0.83 to transform K to K2O and 0.43 for P to P2O5.
Then: Mineral fertilisers are mostly mechanical mixes of water soluble salts of the desired cations like potassium K+, magnesium Mg2+, and Calcium Ca2+. Since these cations are positively charged you also need a counter-charge or anions which are negatively charged. In fertilisers, primarily nitrates (NO3(-)), sulphates (SO4) and phosphorous (mostly as phosphates due to higher solubility PO4(3-).
Nitrogen can be present as ammonium NH4+ or nitrate NO3- (lets forget nitrite its poisonous)and possibly urea that is not a salt but an organic molecule
Suphur mostly as suphates SO4(2-)
Phosphor mostly as phosphate (PO4(3-)
And there are all the other ingredients that make up the fertiliser mix. like borates molybdates etc all containing oxygen.
All this oxygen is not accounted for in the NPK and that is the main reason for not getting to 100 if you start counting ppm's. Take 100g Potassium nitrate (KNO3)as an example. 100g dissolved in 100liter gives 100/100000 =1000ppm These 1000 ppm becomes : 13,9N + 38,7K (46,6 in US)+ 47,4 O
So when you sum up my ppm to 233 out of 400 (=41,8% missing), you get pretty close to the result using potassium nitrate above(47.4% Oxygen) Using other oxygen bearing substances than potassium nitrate makes things more complicated and explains the deviation.
Then Calcium: When salts are dissolved in water they are broken up to cations and anions. The cations are positively charged and are typically metals like K, Mg, Ca, the anions are negatively charged and are typically of non-metals like Nitrogen and Oxygen and Sulphur or Phosporous etc. Ok, the solubility of salts are variable and the least soluble combination tends to precipitate if two solutions are mixes. So in the case of mixing calcium nitrate that has a solubility of more than 100g/100g water (as hydrate) with Potassium sulphate that dissolves 12g/100g water, what happens if you mix equal amounts of say 10% solutions (10g salt in 100g liquid)?
the total volume gets 200ml and the individual concentrations of calciumnitrate and potassium sulphate becomes 5% each. So far so good???
NO! Since calcium sulphate has a solubility of less than 0.2g/100g water, most of the calcium together with suphate will precipitate and get lost as fertiliser. The solubility of calcium sulphate is still some 2000ppm, so it does not precipitate if it is added as calcium nitrate at the nozzle, or for that sake in the bulk volume of water. BUT you cannot mix it in a stock solution.:evil:
This treatise was a bit simplified, if any out there discovers my shortcuts then bear over with me, but its not that easy to popularise the stuff.
If you have questions regarding these things then do not hesitate to ask.