This is a hirsutissimum that has been slowly yellowing. All the plants around it seem happy enough. But based on the water report from my city, I thought the yellowing may be due to insufficient nutrients. Nitrates and nitrites combined are <0.30, Cal/MG 18/1.9, orthophosphates <0.01, pH 8.3. While I am waiting for new fertilizer to arrive I went on and added Cal/Mg and phosphoric acid to my water. Within about six hours I noticed this spot. There is nothing on the underside. It smells of fermenting cider. Something I did to the water? Erwinia? And if so, physan 20 or phyton 27. I am worried about phytotoxicity with the 27. I have on hand copper octonoate. Will this do anything? The plant is already in quarantine. Appreciate any thoughts on this.