Somewhere the Math was off by a lot to jump from 600ppm to 1600ppm so this is good to talk through.
I was computing backwards from N and forgot that the N is as NO3. A nitrate molecule is 4.4X the weight of just the N.
So 100 ppm of N starts out with a mass of 440 mg/L. Now start adding in all the Ca/Mg, and associated anions. So rather than adding it back up bit by bit, I just looked at the table from Ray's website.
Also as long as you know the mass per gallon (1.45g/Gal) just divide that by 3.785 to put that into mg/L. 0.383g/L
There's also waters of hydration that make up the mass of material in a teaspoon, but that won't get picked up by a TDS meter. The TDS meter would probably end up picking up about 600-650 mg/L of the 770 mg/L in a 1/2 tsp to make up 100ppm N K lite.
So in RO or rain water, to get 200 ppm N you'd weigh up 1540 mg/L, but the meter would probably see about 1200ppm of it.